Title
A two step method for the preparation of carbamate cross-linked cellulose films using an ionic liquid and their water retention properties
Document Type
Article
Publication Date
12-10-2016
Abstract
Carbamate cross-linked cellulose films can be prepared in a two step method using cellulose dissolved in 1-n-butyl-3-methylimidazolium chloride ionic liquid. The new technique involves casting the film from cellulose ionic liquid solution onto a glass surface and application of alkyl/aryl diisocyanate in dry dimethylsulfoxide solution onto the cellulose – ionic liquid coating on glass and allowing the cross-linking reaction to occur on the pre-formed cellulose coating. The carbamate cross-linked cellulose films formed were characterized by FT-IR, and TG-DTA. The water retention values of the films are shown to decrease with the increase in hydrophobicity of the alky/aryl group linker in the carbamate bridges.
Recommended Citation
Amarasekara, A., Hasan, M., & Ha, U. (2016). A two step method for the preparation of carbamate cross-linked cellulose films using an ionic liquid and their water retention properties. Retrieved from https://digitalcommons.pvamu.edu/chemistry-physics-facpubs/57