Title
Vanillin-based polymers: IV. Hydrovanilloin epoxy resins
Document Type
Article
Publication Date
1-20-2019
Abstract
In this study, hydrovanilloin synthesized by electrochemical dimerization of vanillin has been used as a renewable substitute for bisphenol A for the preparation of epoxy resins. The reaction of the disodium salt of hydrovanilloin:epichlorohydrin 1:2 mol ratio at 80°C for 30 min in water gave a hydrovanilloin – diglycidyl ether phenoxy resin. This hard thermoplastic resin showed Tg of 135°C and stable up to 255°C in air. On the other hand, the disodium salt of hydrovanilloin:epichlorohydrin 1:4 mol ratio at 80°C for 30 min in water gives a curable oligomer of hydrovanilloin – diglycidyl ether with 2.1 repeating units. This oligomer could be cured with aliphatic diamines: 1,2-diaminoethane, 1,4-diaminobutane, 1,6-diaminohexane, and isophorone diamine to give hard epoxy resins with Tg values of 116, 118, 149 and 146°C, respectively. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47000.
Recommended Citation
Amarasekara, A., Garcia-Obergon, R., & Thompson, A. (2019). Vanillin-based polymers: IV. Hydrovanilloin epoxy resins. Retrieved from https://digitalcommons.pvamu.edu/chemistry-physics-facpubs/47