Title

Synthesis and Study of Head-to-Tail Regioregular Poly(alkyl thiophene-3-carboxylates)

Document Type

Article

Publication Date

1-1-2003

Abstract

Regioregular head-to-tail poly(alkyl thiophene-3-carboxylates) have been prepared by very careful formation of the mono-Grignard reagent from alkyl 2,5-dibromothiophene-3-carboxylates (-40°C, 1 h) followed by nickel-catalyzed polymerization. The spectral properties are reported along with the molecular weights.

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